Analysis of Trace Metals in Groundwater from Mountain Springs
Analysis of Trace Metals in Groundwater from Mountain Springs
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Abstract
This study aimed to estimate the concentrations of several heavy metals, including cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb), and zinc (Zn), in fifteen springs around the Soran Independent Administration, Kurdistan Region of Iraq. Water samples were collected during two seasons (summer 2024 and winter 2025) and analyzed using inductively coupled plasma optical emission spectroscopy (ICP-OES). The results showed that most trace metals had higher concentrations in winter than in summer. The concentration ranges were: Cd (0.011–0.678 mg/L), Cr (0.300–0.548 mg/L), Cu (0.417–0.645 mg/L), Fe (0.022–0.199 mg/L), Mn (0.007–0.123 mg/L), Ni (0.002–0.047 mg/L), Pb (0.005–0.149 mg/L), and Zn (0.010–0.109 mg/L). Except for cadmium and chromium, which exceeded safe limits at all sites, the concentrations of most metals were generally below WHO guidelines for drinking water; however, lead at some sites also rendered the water unsuitable for drinking. According to the Heavy Metals Pollution Index (HPI), values above 100 in all studied springs (ranging from 405.94 to 16023.72 in summer and 811.12 to 1780.97 in winter) indicated contamination and unsuitability for human use. In contrast, based on the Metal Index (MI), most trace metals had values below 1, indicating no contamination. However, MI values for cadmium and chromium above 5 signified heavy pollution, and MI values for lead ranged from 0.5 to 22.2, varying from uncontaminated to heavily polluted. Based on these findings, this study recommends: (1) regular monitoring of Cd, Cr, and Pb concentrations; (2) implementation of pollution control measures, including regulated use of fertilizers and pesticides in surrounding agricultural areas; and (3) adoption of point-of-use water treatment systems for communities relying on these springs for drinking water
References
- H. A. Ameen, "Spring water quality assessment using water quality index in villages of Barwari Bala, Duhok, Kurdistan Region, Iraq," Appl. Water Sci., vol. 9, no. 8, pp. 176-188, 2019, DOI: 10.1007/s13201-019-1080-z
- J. Toma and M. Othman, "Determination of the trace metals in Bottled Water That Is Available in Erbil City, Iraq, J. Environ. Stud., vol. 6, no. 1, pp. 31-37, 2011.
- J. J. Toma and F. H. Aziz, "Heavy metals compositions in springs and streams from Shaqlawa district, Erbil Province, Kurdistan region of Iraq," Zanco J. Pure Appl. Sci., vol. 34, no. 4, pp. 45-52, 2022, DOI: 10.25130/tjps.v29i2.1592
- T. Taha, "Clay mineralogy and heavy metal geochemistry of the Tigris River sediments in selected areas of northern Iraq," Tikrit J. Pure Sci., vol. 28, pp. 107-116, Oct. 2023. DOI: 10.25130/tjps.v28i5.1081
- Q. Li, Z. Han, Y. Tian, H. Xiao, and M. Yang, "Risk assessment of heavy metal in farmlands and crops near Pb–Zn mine Tailing Ponds in Niujiaotang, China," Toxics, vol. 11, no. 2, pp. 106-124, 2023, DOI: 10.3390/toxics11020106
- S. A. Al-Asadi, W. S. Al-Qurnawi, A. B. Al Hawash, H. B. Ghalib, and N.-H. A. Alkhlifa, "Water quality and impacting factors on heavy metals levels in Shatt Al-Arab River, Basra, Iraq," AAppl. Water Sci., vol. 10, no. 5, pp. 1-15, 2020. DOI:10.1007/s13201-020-01196-1
- Z. Salih, J. Toma, A. Aziz, T. Hassan, and F. Aziz, "Evaluation of Rainwater Quality in Some Polluted Locations within Erbil Province," Pol. J. Environ. Stud., vol. 33, no. 2, pp. 1839-1848, 2024. DOI:10.15244/pjoes/173997
- V. M. Wagh, D. B. Panaskar, S. V. Mukate, S. K. Gaikwad, A. A. Muley, and A. M. Varade, "Health risk assessment of heavy metal contamination in groundwater of Kadava River Basin, Nashik, India," Model. Earth Syst. Environ.,vol. 4, pp. 969-980, 2018. DOI: 10.1007/s40808-018-0496-z
- J. J. Toma and F. H. Aziz, "New records of algae in Shaqlawa district, Erbil, Kurdistan region of Iraq," Al-Nahrain J. Sci., vol. 24, no. 3, pp. 55-62, 2021. DOI:10.21123/bsj.2023.7657
- W. C. Lipps, E. B. Braun-Howland, and T. E. Baxter, Standard methods for the examination of water and wastewater. American Public Health Association, 2023. 10.2105/SMWW.2882.086
- A. Mughal et al., "Risk analysis of heavy metals and groundwater quality indices in residential areas: a case study in the Rajanpur District, Pakistan," Water, vol. 14, no. 21, pp. 139-157, 2022. DOI:
- 3390/w14213551
- H. Xie, X. Yang, J. Xu, and D. Zhong, "Heavy metals pollution and potential ecological health risk assessment in the Yangtze River reaches," J. Environ. Chem. Eng., vol. 11, no. 2, pp. 109489-109514, 2023. DOI: 10.1016/j.heliyon.2024.e30739
- W. H. Organization, Guidelines for drinking-water quality: incorporating the first and second addenda. World Health Organization, 2022.
- H. S. Ghalib and M. M. Ramal, "Spatial and temporal water quality evaluation of heavy metals of Habbaniyah Lake, Iraq," Int. J. Des. Nat. Ecodynamics, vol. 16, no. 4, pp. 467-475, 2021. DOI: https://doi.org/10.18280/ijsdp.160715
- S. H. Muhyadeen and R. A. Ramadhan, "Outdoor Air Contaminants-Heavy Metals and Associated Health Risks in Duhok-Iraq," Sci. J. Univ. Zakho, vol. 11, no. 1, pp. 78-83, 2023. DOI: 10.25271/sjuoz.2023.11.1.1043
- A. Kannah and H. Shihab, "A Study of Some Physical and Chemical Properties of the water of the Tigris River within the city of Mosul, Iraq," J. Educ. Sci., vol. 34 pp. 2021-1458, 08/11 2022. DOI: 10.33899/jes.v34i4.49251
- K. Khwedim, M. T. Ahmed, and M. A. Najemalden, "Survey of some heavy metals and radioactivity in the dust in a selected area in Kirkuk Governorate-Northern Iraq," Iraqi J. Sci., pp. 3817-3824, 2022.
- B. Mahdi, K. Yousif, and L. S. Dosky, "Characterization of airborne particles collected in Duhok city (in Iraq), by using various techniques," IOP Conf. Ser.: Mater. Sci. Eng., vol. 454, no. 1, pp. 012073-012098 2018 DOI: 10.25271/sjuoz.2023.11.1.1043
- J. J. Toma, "Trace metal composition in Ainkawa groundwater, Erbil. Kurdistan of Iraq," Zanco J. Pure Appl. Sci., vol. 20, no. 2, pp. 65-74, 2008.
- A. M. Kannah and F. Shihab, "Heavy metals levels in the water of the Tigris River in the City of Mosul, Iraq," Egypt. J. Aquat. Biol. Fish, vol. 26, no. 6, pp. 1007-1020, 2022.
- M. F. Abed, G. A. Zarraq, and S. H. Ahmed, "Assessment of groundwater pollution using aqueous geo-environmental indices, Baiji Province, Salah Al-Din, Iraq," Iraqi Geol. J., , vol. 1, no. 2, pp. 94-104, 2022. DOI: 10.25130/tjes. 30.1.3
- A. A. Al-Kinani and A. J. Al-Azawi, "Study of the effect of agricultural and domestic pollutants on the water quality of the Diyala River in Iraq," Int. J. Health Sci., no. II, pp. 9092-9098, 2022. DOI: 10.53730/ijhs.v6nS2.7374
- S. Jalal, "Exploring the Distribution of Microplastics and Heavy Metals in Agricultural Soils and the Evaluation of Risk Indices in Erbil City," J. Educ. Sci., vol. 34, p. 4, 10/01 2025. DOI: 10.33899/jes.v34i4.49251
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