Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline

New complexes of general formula [M(LXSBu'')2],[M(L)(SFur)z]and adducts [M(L)(SBu")2(phen)]. [M(L)(SFur)z(phen)l,where L:C is-bis-I .2-(phenylthio)ethylene. SBu'': 1 -butanethiol. SFur:2-furanmethanthiol.phen:1,10 phenanthroline, M:Zn(ll).cd(ll) and FIg(ll) have beenprepared in basic medium. The complexes and adducts wereihaiacterized by atomic absorption, conductivity measurements,spectral(lR and electronic) and molecular weight measurements studies'ietrahedral environment around the metal ions in the complexes andoctahedral geometry in the adducts were suggested according to theabove measurements.